✔ 最佳答案
Refer to:
https://depts.washington.edu/eooptic/links/acidstrength.html
Ka(HF) = 6.6 × 10⁻⁴
Hence, Kb(F⁻) = Kw / Ka(HF) = (1.0 × 10⁻¹⁴) / (6.6 × 10⁻⁴) = 1.52 × 10⁻¹¹
(Ka value from different sources may be slightly different.)
Consider the dissociation of F⁻.
F⁻(aq) + H₂O(ℓ) ⇌ HF(aq) + OH⁻(aq) Kb = 1.52 × 10⁻¹¹
Initial (M): 0.370 --- 0 0
Change (M): -y --- +y +y
Eqm (M): 0.0370 - y --- y y
≈ 0.370 (as Kb is very small)
At equilibrium:
Kb = [HF] [OH⁻] / [F⁻]
1.52 × 10⁻¹¹ = y² / 0.370
y = √(0.370 × 1.52 × 10⁻¹¹)
[OH⁻] = y M = 2.37 × 10⁻⁶ M
pH = Kw - pOH = 14.00 + log(2.37 × 10⁻⁶) = 8.37