Plug u=5x back in and note that du/dx = 5
d/dx (5x)^n = 5n * (5x)^(n-1)
The constant term in that sum on the right vanishes and the derivatives of the next 5 terms follow the above pattern. When simplifying, you'll find that n/n! will reduce to 1/(n-1)! in each term, so that you end up 5 times the original series.
...which is just what you should expect from using the chain rule d/dx e^(5x) directly, without expanding the power series.