The solubility of Ag3PO4 is 2.1x10-4 g/100g water.?

2020-11-20 9:52 am
1) Write the equation showing the dissolution of this ionic solid.


2) Calculate the molarity of this saturated solution.



3) What is the value of Ksp for this system?

回答 (1)

2020-11-20 11:31 am
✔ 最佳答案
1)
Ag₃PO₄(s) ⇌ 3Ag⁺(aq) + PO₄³⁻(aq)

2)
Density of water = 1 g/mL
Volume of the solution = (100 g) × (1 g/mL) = 100 mL = 0.1 L
Molar mass of Ag₃PO₄ = (107.9×3 + 31.0 + 16.0×4) g/mol = 418.7 g/mol
Molarity = [(2.1 × 10⁻⁴)/418.7 mol] / (0.1 L) = 5.0 × 10⁻⁶ M

3)
Ksp = [Ag⁺]³ [PO₄³⁻] = (3 × 5.0 × 10⁻⁶)³ × (5.0 × 10⁻⁶) = 1.7 × 10⁻²⁰


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