✔ 最佳答案
Method 1:
Consider the S₈ vapor reacted:
Pressure, P = 8.87 atm
Volume, V = 6.3 L
Temperature, T = (273 + 655) K = 928 K
Gas constant, R = 0.08206 L atm / (mol K)
Gas law: PV = nRT
Then, n = PV/(RT)
Moles of S₈ reacted, n = 8.87 × 6.3 / (0.08206 × 928) mol = 0.7338 mol
Moles of SO₂ obtained = 0.7338 × 8 = 5.8704 mol
Molar mass of SO₂ = (32.1 + 16.0×2) g/mol = 64.1 g/mol
Mass of SO₂ obtained = (5.8704 mol) × (64.1 g/mol) = 376.3 g
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Method 2:
At constant temperature and pressure, volume ratio of gases is equal to their mole ratio.
Balanced equation for the reaction:
S₈ + 8O₂ → 8SO₂
Volume ratio S₈ : SO₂ = 1 : 8
Volume of SO₂ obtained = (6.3 L) × 8 = 50.4 L
Consider the SO₂ gas obtained:
Pressure, P = 8.87 atm
Volume, V = 50.4 L
Temperature, T = (273 + 655) K = 928 K
Molar mass, M = (32.1 + 16.0×2) g/mol = 64.1 g/mol
Gas constant, R = 0.08206 L atm / (mol K)
PV = nRT and n = m/M
Then, PV = (m/M)RT
m = PVM/(RT)
Mass of SO₂ produced, m
= 8.87 × 50.4 × 64.1 / (0.08206 × 928) g
= 376.3 g