✔ 最佳答案
At constant temperature and pressure, volume ratio of gases is equal to their mole ratio.
N₂(g) + 3H₂(g) → 2NH₃(aq)
Volume ratio N₂ : H₂ = 1 : 3
If N₂ completely reacts, H₂ needed = (5.84 L) × 3 = 17.52 L < 24.96 L
Hence, H₂ is in excess, and the limiting reactant is N₂.
According to the above equation, volume ratio N₂ : NH₃ = 1 : 2
Volume of NH₃ formed = (5.84 L) × 2 = 11.68 L
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OR:
If H₂ completely reacts:
(5.84 L N₂) × (2 L NH₃ / 1 L N₂) = 11.68 L NH₃
If N₂ completely reacts:
(24.96 L H₂) × (2 L NH₃ / 3 L H₂) = 16.64 L NH₃
When completely reacts, the limiting reactant produces the smallest amount of product.
Hence, H₂ is the limiting reactant.
Volume of NH₃ formed = 11.68 L