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If you've never bleached your hair before, I would suggest going to a professional and having them do it, specially if you have dark hair or previously dyed hair.
Get bleach powder and developer from a beauty supply store.
Read and follow the instructions carefully, never leave bleach on your hair for longer then the instructions says to, also mix the powder and developer as directed.
Wear some old clothes that you don't care about getting stained, also wear gloves and don't use anything metal, your mixing utensils should be plastic and or ceramic.
After you bleach your hair use a hair toner to remove any brassiness, and use a deep conditioner after you bleach it and after toning your hair.
There's a bunch of you tube tutorials around on bleaching your hair at home, try watching a few of them before you do it.