✔ 最佳答案
HBr is a strong acid. Each mole of HBr completely ionizes to give 1 mole of H₃O⁺.
[H₃O⁺] from HBr = [HBr]ₒ = 1.3 × 10⁻⁹ M
[H₃O⁺] form HBr is too small. Hence, the ionization of water must be considered.
2H₂O(ℓ) ⇌ H₃O⁺(aq) + OH⁻ Kw = 1.0 × 10⁻¹⁴
Initial (M): -- 1.3×10⁻⁹ 0
Change (M): -- +y +y
Eqm (M): -- (1.3×10⁻⁹ + y) y
At equilibrium:
Kw = [H₃O⁺] [OH⁻]
1.0 × 10⁻¹⁴ = (1.3 × 10⁻⁹ + y) y
y² + (1.3 × 10⁻⁹)y - (1.0 × 10⁻¹⁴) = 0
y = {-(1.3 × 10⁻⁹) ± √[(1.3 × 10⁻⁹)² + 4*(1.0 × 10⁻¹⁴)] / 2
y = 9.94 × 10⁻⁸ or y = -1.01 × 10⁻⁷ (rejected)
[H₃O⁺] = (1.3 × 10⁻⁹ + 9.94 × 10⁻⁸) M = 1.007 × 10⁻⁷ M
pH = -log[H₃O⁺] = -log(1.007 × 10⁻⁷) = 7.00