✔ 最佳答案
Molar mass of Pb²⁺ = 207.2 g/mol
Molar mass of NaCl = (22.99 + 35.45) g/mol = 58.44 g/mol
Molar mass of PbCl₂ = (207.2 + 35.45×2) g/mol = 278.1 g/mol
Initial moles of Pb²⁺ = (195.7 g) / (207.2 g/mol) = 0.9445 mol
Initial moles of NaCl = (135.8 g) / (58.44 g/mol) = 2.324 mol
Equation for the reaction:
Pb²⁺(aq) + 2NaCl → PbCl₂ + 2Na⁺
Mole ratio Pb²⁺ : NaCl = 1 : 2
If Pb²⁺ completely reacts, NaCl needed = (0.9445 mol) × 2 = 1,889 mol < 2.324 mol
Hence, NaCl is in excess, and the limiting reactant is Pb²⁺.
According to the above equation, mole ratio Pb²⁺ : PbCl₂ = 1 : 1
Maximum moles of PbCl₂ yielded = 0.9445 mol
Theoretical yield of PbCl₂ = (0.9445 mol) × (278.1 g/mol) = 262.7 g
Percent yield of the reaction = (225.4/262.7) × 100% = 85.80%