Calculate the [OH−]   and the pH   of a solution with an [H+]=0.0071 M   at 25 °C  .?

2020-08-03 11:56 pm

回答 (2)

2020-08-04 12:35 am
[OH⁻] = Kw/[H⁺] = (1 × 10⁻¹⁴)/0.0071 M = 1.41 × 10⁻¹² M

pH = -log[H⁺] = -log(0.0071) = 2.15
2020-08-04 12:11 am
Given,

[H+] = 0.0071 M

Autoionization constant of water, Kw = 10-14 at 25 oC

Now,

Kw = [H+][OH-] = 10-14

or, [OH-] = 10-14/(0.0071)

              = 1.408 x 10^-12M

Hence, the concentration of OH- = 1.408 x 10^-12 M

Now,

pH = 14 - pOH

     = 14 + log[OH-]

     = 14 + log(1.408 x 10^-12)

     = 14 - 11.85

     = 2.14


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