What's the pH of a 0.1 M HIO solution knowing that its pKa = 10.4?
回答 (2)
pKa = 10.4, and thus Ka = 10⁻¹⁰·⁴
HIO + H₂O(ℓ) ⇌ IO⁻(aq) + H₃O⁺(aq) Ka = 10⁻¹⁰·⁴
Initial: 0.1 M 0 M 0 M
Change: -y M +y M +y M
Eqm: (0.1 - y) M y M y M
≈ 0.1 M
At equilibrium :
Ka = [IO⁻] [H₃O⁺] / [HIO]
10⁻¹⁰·⁴ = y² / 0.1
y = √(0.1 ×10⁻¹⁰·⁴) = 2.00 × 10⁻⁶
pH = -log[H₃O⁺] = -log(2.00 × 10⁻⁶) = 5.7
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OR:
pH = (1/2)(pKa - log[HIO]ₒ) = (1/2)(10.4 - log(0.1)) = 5.7
with weak acids we can use this simple equation
H+ = sqrt ( Ka * c)
H+= sqrt 10 ^-10.4* 0.1) = 2.00E-06
pH = 5.7
收錄日期: 2021-04-21 14:08:30
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