Calculate the solubility of magnesium fluoride, MgF2, in water by knowing the Ksp = 5.2 x 10-11?
回答 (2)
_ MgF₂(s) ⇌ Mg²⁺(aq) + 2F⁻(aq) Ksp = 5.2 × 10⁻¹¹
_Initial: 0 M 0 M
_Change: +s M +2s M
_Eqm: s M 2s M
At equilibrium:
Ksp = [Mg²⁺] [F⁻]²
5.2 × 10⁻¹¹ = s (2s)²
4s³ = 5.2 × 10⁻¹¹
s = ³√(5.2 × 10⁻¹¹ / 4)
s = 2.4 × 10⁻⁴
Solubility of MgF₂ in water = 2.4 × 10⁻⁴ M
MgF2 = Mg2+ + 2OH-
Ksp = [Mg2+] * [OH-]^2
if x mole of the hydroxide dissolves we have
x * (2x)^2 = 5.2 x 10-11
4 x^3 = 5.2 x 10-11
x^3 = 1.3 * 10^-11
x = 2.35 * 10 ^-4 = moles of MgF2 that dissolved/ liter
molar solubility of MgF2 = 2.35 * 10 ^-4
收錄日期: 2021-04-24 07:54:24
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