✔ 最佳答案
Molar mass of HC₆H₅CO₂ = (1.0×6 + 12.0×7 + 16.0×2) g/mol = 122.0 g/mol
Initial concentration of HC₆H₅CO₂ = (2.12/122.0 mol) / (1.2 L) = 0.01448 M
pH = log[H₃O⁺] = 2.75
Hence, [H₃O⁺] at equilibrium = 10⁻²˙⁷⁵ M = 0.001778 M
Consider the dissociation of HC₆H₅CO₂:
_ HC₆H₅CO₂(aq) + H₂O(ℓ) ⇌ C₆H₅CO₂⁻(aq) + H₃O⁺(aq) Kₐ = ?
_Initial: 0.01448 M 0 M 0 M
_Change: -y M +y M +y M
_Equilibrium: (0.01448 - y) M y M y M
At equilibrium:
[H₃O⁺] = y M = 0.001778 M
y = 0.001778
Kₐ for the dissociation of HC₆H₅CO₂
= [C₆H₅CO₂⁻] [H₃O⁺] / [HC₆H₅CO₂]
= y² / (0.01448 - y)
= 0.001778² / (0.01448 - 0.001778)
= 2.49 × 10⁻⁴