chemistry hw?
A 1.50 mole sample of PCl3 and 1.0 mole sample of Cl2 are placed in a 1.00 M reaction vessel. If Kc for this reaction is 1.80 at 250 C, what are the concentrations of all substances at equilibrium?
PCl3 (g) + Cl2 (g) ⇄ PCl5 (g)
回答 (2)
Suppose that the samples are placed in a 1.00 L reaction vessel instead.
_ PCl₃(g) + Cl₂(g) ⇌ PCl₅(g) Kc = 1.80
Initial: 1.5 M 1 M 0 M
Change: -y M -y M +y M
Eqm: (1.5 - y) M (1 - y) M y M
At equilibrium:
Kc = [PCl₅] / ([PCl₃] [Cl₂])
1.8 = y / [(1.5 - y)(1 - y)]
1.8 = y / (y² - 2.5y + 1.5)
1.8(y² - 2.5y + 1.5) = y
1.8y² - 5.5y + 2.7 = 0
y = [5.5 ± √(5.5² - 4×1.8×2.7)] / (2×1.8)
y = 2.44 (rejected) or y = 0.614
At equilibrium:
[PCl₃] = (1.5 - 0.614) M = 0.886 M
[Cl₂] = (1 - 0.614) M = 0.386 M
[PCl₅] = 0.614 M
I'm going to assume that you meant that the vessel was 1.00 L in volume.
Kc = [PCl5]/[PCl3][Cl2] = 1.80
Let equilibrium concentration of PCl5 = x. Then, [PCl3] = 1.50-x and [Cl2] = 1.00-x
Then,
Kc = 1.80 = x / (1.50-x)(1.00-x)
Now, I'll leave the math up to you. You will need to rearrange this equation in the a quadratic with the form ax^2 + bx + c = 0 and use the quadratic formula to find x. Once you have x, you can easily calculate the concentrations.
收錄日期: 2021-04-18 18:31:50
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