Chm question?

2020-05-11 2:36 pm

回答 (1)

2020-05-11 4:24 pm
Cd²⁺(aq) + Fe(s) → Cd(s) + Fe²⁺(aq)     E° = 0.0400 V

Nernst equation:
E = E° - {RT/(nF)} ln([Fe²⁺]/[Cd²⁺])
0.000 = 0.0400 - {8.314 × 298 / (2 × 96485)} ln([Fe²⁺]/[Cd²⁺])
{8.314 × 298 / (2 × 96485)} ln([Fe²⁺]/[Cd²⁺]) = 0.0400
ln([Fe²⁺]/[Cd²⁺]) = 3.1155
[Fe²⁺]/[Cd²⁺] = e³˙¹¹⁵⁵
[Fe²⁺]/[Cd²⁺] = 22.5


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