✔ 最佳答案
2 MnO4{-} + 16 H{+} + 5 Na2C2O4 →
10 CO2(g) + 2 Mn{2+}(aq) + 8 H2O(l) + 10 Na{+}
(0.342 g Na2C2O4) / (133.9985 g Na2C2O4/mol) x
(2 mol MnO4{-} / 5 mol Na2C2O4) / (50.3 mL) = 2.0296 × 10^-5 mol MnO4{-} / mL
UO{2+}→UO2{2+} = U{4+} → U{6+}
5 U{4+} + 2 MnO4{-} + 16 H{+} → 2 Mn{2+} + 5 U{6+} + 8 H2O
(32.0 mL) × (2.0296 × 10^-5 mol MnO4{-} / mL) × (5 mol U / 2 mol MnO4{-}) ×
(238.02891 g U/mol) / (4.60 g total) = 0.084018 = 8.40% U by mass