chem help needed?

2020-04-17 2:15 pm
A student performs a titration using 10.00 mL of 0.08991 M HCl with 0.07613 M NaOH.

Determine the pH at each of the following addition of the NaOH

a)0.00 mL of NaOH. 
b)5.91 mL of NaOH
c)The addition of NaOH to reach the equivalence point
d)15.00 mL of NaOH

回答 (1)

2020-04-17 2:59 pm
a)
[H₃O⁺] = 0.08991 M
pH = -log[H₃O⁺] = -log(0.08991) = 1.05

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b)
Initial moles of H₃O⁺ = (0.08991 mol/L) × (10.00/1000 L) = 0.0008991 M
Moles of OH⁻ = (0.07613 mol/L) × (5.91/1000) = 0.0004499 M
Volume of the final solution = (10.00 + 5.91) mL = 15.91 mL = 0.01591 L

H₃O⁺(aq) + OH⁻(aq) → 2H₂O(ℓ)
H₃O⁺ is in excess.
In the final solution, [H₃O⁺] = (0.0008991 - 0.0004499)/0.01591 M = 0.02823 M
pH = -log[H₃O⁺] = -log(0.02823) = 1.55

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c)
All the equivalence point, both H₃O⁺ and OH⁻ completely react. The final solution is the solution of NaCl which is neutral.
Hence, pH = 7.00

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d)
Initial moles of H₃O⁺ = 0.0008991 M
Moles of OH⁻ = (0.07613 mol/L) × (15.00/1000) = 0.001142 M
Volume of the final solution = (10.00 + 15.00) mL = 25.00 mL = .025 L

H₃O⁺(aq) + OH⁻(aq) → 2H₂O(ℓ)
OH⁻ is in excess.
In the final solution, [OH⁻] = (0.001142 - 0.0008991)/0.025 M = 0.09716 M
pOH = -log[OH⁻] = -log(0.09716) = 2.01
pH = pKw - pOH = 14.00 - 2.01 = 11.99


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