What is the [OH-] in a 0.25M hypobromous acid(HOBr) solution?Ka=2.5x10^-9
Here are the choices:?
a. 4.0x10^-10 M
b. 2.5x10^-9 M
c. 1.0x10^-7 M
d. 2.5x10^-5 M
e. 2.0x10^-10 M
回答 (2)
_________ HOBr + H₂O(ℓ) ⇌ OBr⁻(q) + H₃O⁺(aq) __ Ka = 2.5 × 10⁻⁹
Initial: 0.25 M 0 M 0 M
Change: -y M +y M +y M
Eqm: (0.25 - y) M y M y M
_ ≈ 0.25 M
At equilibrium :
Ka = [OBr⁻] [H₃O⁺] / [HOBr]
2.5 × 10⁻⁹ = y² / 0.25
y = √(0.25 × 2.5 × 10⁻⁹) = 1.4 × 10⁻³
[H₃O⁺] = 2.5 × 10⁻⁵ M
[OH⁻] = Kw/[H₃O⁺] = (1.0 × 10⁻¹⁴)/(2.5 × 10⁻⁵) M = 4.0 × 10⁻¹⁰ M
The answer: a. 4.0 × 10⁻¹⁰ M
HBrO <--> H+ + BrO-
Ka = [H+][BrO-] / [HBrO]
2.5x10^-9 = x^2 / 0.25
x = 2.5x10^-5 M = [H+]
Kw = [H+][OH-] = 1x10^-14
[OH-] = 1x10^-14 / 2.5x10^-5 = 4.0x10^-10 M <<< answer
收錄日期: 2021-04-18 18:26:28
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