A sample of 5.31 g of liquid 1‑propanol, C3H8O, is combusted with 46.4 g of oxygen gas. Carbon dioxide and water are the products.?
Write the balanced chemical equation for the reaction.
What is the limiting reactant?
1‑propanol
oxygen
How many grams of CO2 are released in the reaction?
mass of CO2 :
g
How many grams of the excess reactant remain after the reaction is complete?
mass of excess reactant remaining:
回答 (2)
Molar mass of C₃H₈O (1- propanol) = (12.0×3 + 1.0×8 + 16.) g/mol = 60.0 g/mol
Molar mass of O₂ (oxygen) = 16.0×2 g/mol = 32.0 g/mol
Molar mass of CO₂ (carbon dioxide) = (12.0 + 16.0×2) = 44.0 g/mol
Initial number of moles of C₃H₈O = (5.31 g) / (60 g/mol) = 0.0885 mol
Initial number of moles of O₂ = (46.4 g) / (32.0 g/mol) = 1.45 mol
2C₃H₈O + 9O₂ → 6CO₂ + 8H₂O
Molar ratio C₃H₈O : O₂ : CO₂ = 2 : 9 : 6
If C₃H₈O completely combusts, O₂ needed = (0.0885 mol) × (9/2) = 0.398 mol < 1.45 mol
Hence, O₂ is in excess, and C₃H₈O (1-propanol) is the limiting reactant.
Number of moles of C₃H₈O reacted = 0.0885 mol
Number of moles of CO₂ produced = (0.0885 mol) × (6/2) = 0.2655 mol
Mass of CO₂ produced = (0.2655 mol) × (44.0 g/mol) = 11.7 g
Number of moles of excess O₂ reacted = 0.398 mol
Mass of excess O₂ remained = [(1.45 - 0.398) mol] × (32 g/mol) = 33.7 g
Combustion .....
Only a gas undergoes combustion. When solving a limiting reactant problem you can compute the amount of product using each reactant. The lesser amount is the theoretical yield and tells the limiting reactant.
2C3H7OH(g) + 9O2(g) --> 6CO2(g) + 8H2O(g)
5.31g ............... 46.4g ...........?g
5.31g C3H7OH x (1 mol C3H7OH / 60.09g C3H7OH) x (3 mol CO2 / 1 mol C3H7OH) x (44.0g CO2 / 1 mol CO2) = 11.7g CO2
46.4g O2 x (1 mol O2 / 32.0g O2) x (2 mol CO2 / 3 mol O2) x (44.0g CO2 / 1 mol CO2) = 42.5g CO2
A mass of 11.7g of CO2 is produced, and propanol is the limiting reactant.
5.31g C3H7OH x (1 mol C3H7OH / 60.09g C3H7OH) x (9 mol O2 / 2 mol C3H7OH) x (32.0g O2 / 1 mol O2) = 12.7g O2 .... reacts
Excess O2 = 46.4g - 12.7g = 33.7g O2
收錄日期: 2021-04-24 07:30:34
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