the rate of the reaction?

2019-02-13 1:43 pm
Consider the single-step, bimolecular reaction.

CH3Br+NaOH⟶CH3OH+NaBr

When the concentrations of CH3Br and NaOH are both 0.165 M , the rate of the reaction is 0.0010 M/s .

What is the rate of the reaction if the concentration of CH3Br is doubled?What is the rate of the reaction if the concentrations of CH3Br and NaOH are both increased by a factor of 3?

回答 (1)

2019-02-13 3:55 pm
✔ 最佳答案
CH₃Br + NaOH → CH₃OH + NaBr
As the reaction is single-step bimolecular, the rate determination step is as same as the chemical equation, and
the rate law is: Rate = k [CH₃Br] [NaOH]

When the concentrations of CH3Br and NaOH are both 0.165 M , the rate of the reaction is 0.0010 M/s
0.0010 = k (0.165) (0.165) …… {1}

When concentration of CH₃Br is doubled:
Rate = k (0.165×2) (0.165) …… {2}
(2)/{1}: Rate/0.0010 = 2
Rate = 0.0020 M/s

When the concentrations of CH₃Br and NaOH are both increased by a factor of 3:
Rate = k (0.165×3) (0.165×3) …… {3}
{3}/{1}: Rate/0.0010 = 9
Rate = 0.0090 M/s


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