Calculate the minimum temperature, in kelvin, at which the reaction is spontaneous?

2018-09-29 1:14 am
enthalpy is given and system entropy is given
in this question they equate the gibbs =0 how?

回答 (1)

2018-09-29 1:38 am
When a system is at equilibrium, its Delta G = 0. At any temperature in one direction from the equilibrium temperature, the reaction will be spontaneous, and at any temperature the other side of that equilibrium temperture, the reaction will be non-spontaneous. Both Delta H and Delta S are relatively temperature independent. So, using the equation

Delta G = Delta H - T Delta S, and setting Delta G = 0 will allow you to calculate the temperature at which the reaction is in equilibrium. From the wording of your title, even a very slight increase above this will cause the reaction to be spontaneous.


收錄日期: 2021-04-24 01:13:10
原文連結 [永久失效]:
https://hk.answers.yahoo.com/question/index?qid=20180928171409AAQ7YPx

檢視 Wayback Machine 備份