Solutions of sulfuric acid and lead (ll) acetate react to form solid lead (ll) sulfate and a solution of acetic acid.?

2018-07-27 11:00 pm
If 10.0 g of sulfuric acid and 10.0 g of lead (ll) acetate are mixed, calculate the number of grams of sulfuric acid, lead (ll) acetate, lead (ll) sulfate, and acetate acid present in the mixture after the reaction is complete.

回答 (1)

2018-07-28 12:16 am
✔ 最佳答案
Molar mass of H₂SO₄ = (1.0×2 + 32.1 + 16.0×4) g/mol = 98.1 g/mol
Molar mass of Pb(CH₃COO)₂ = (207.2 + 12.0×4 + 1.0×6 + 16.0×4) g/mol = 325.2 g/mol
Molar mass of PbSO₄ = (207.2 + 32.1 + 16.0×4) g/mol = 303.3 g/mol
Molar mass of CH₃COOH = (12.0×2 + 1.0×4 + 16.0×2) g/mol = 60.0 g/mol

Initial number of moles of H₂SO₄ = (10.0 g) / (98.1 g/mol) = 0.10194 mol
Initial number of moles of (CH₃COO)₂Pb = (10.0 g) / (325.2 g/mol) = 0.03075 mol

H₂SO₄(aq) + Pb(CH₃COO)₂(s) → PbSO₄(aq) + 2CH₃COOH(aq)
Mole ratio H₂SO₄(aq) : Pb(CH₃COO)₂ : PbSO₄ : CH₃COOH = 1 : 1 : 1 : 2

When 0.03075 mol Pb(CH₃COO)₂ completely reacts, H₂SO₄ needed = 0.03075 mol < 0.10194 mol
Hence, H₂SO₄ is excess, and Pb(CH₃COO)₂ is the limiting reagent/reactant.
Number of moles of Pb(CH₃COO)₂ reacted = 0.03075 mol
Number of moles of H₂SO₄ reacted = 0.03075 mol
Number of moles of PbSO₄ produced = 0.03075 mol
Number of moles of CH₃COOH produced = (0.03075 mol) × 2 = 0.0615 mol

After the reaction is complete:
Mass of Pb(CH₃COO)₂ present in the reaction mixture = 0 g (completely reacted)
Mass of H₂SO₄ present in the reaction mixture = [(0.10194 - 0.03075) mol] × (98.1 g/mol) = 6.98 g
Mass of PbSO₄ present in the reaction mixture = (0.03075 mol) × (303.3 g/mol) = 9.33 g
Mass of CH₃COOH present in the reaction mixture = (0.0615 mol) × (60.0 g/mol) = 3.69 g


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