How do you balance REDOX reactions using the Oxidation Number method not the half reaction method step by step in the question below?

2018-05-20 9:29 pm
What is the step step way of using oxidation number method for balancing the following REDOX equation
MnO4- + HO2CCO2H + H+ ->Mn2+ + CO2 + H2O?

回答 (1)

2018-05-20 9:57 pm
✔ 最佳答案
Multiply CO₂ by 2 because there are 2 C atoms on the left. The unbalanced equation is :
MnO₄⁻ + HO₂CCO₂H → Mn²⁺ + 2CO₂

Consider MnO₄⁻ → Mn²⁺ …… [1]
The oxidation number of Mn decreases from +7 to +2.
5e⁻ are gained in the conversion.

Consider HO₂CCO₂H → 2CO₂ …… [2]
The oxidation number of C increases from +3 to +4.
As there are 2 C atoms, 2e⁻ are lost in the conversion.

To eliminate the e⁻, [1]×2 + [2]×5 :
2MnO₄⁻ + 5 HO₂CCO₂H → 2Mn²⁺ + 10CO₂

Add 8H₂O to the right in order to make 28 O atoms on the both sides.
2MnO₄⁻ + 5 HO₂CCO₂H → 2Mn²⁺ + 10CO₂ + 8H₂O

Finally, add 6H⁺ to the left in order to made 16 H atoms on the both sides.
2MnO₄⁻ + 5 HO₂CCO₂H + 6H⁺ → 2Mn²⁺ + 10CO₂ + 8H₂O
(Check: There are 4 positive charges on the both sides.)

The answer:
2MnO₄⁻ + 5 HO₂CCO₂H + 6H⁺ → 2Mn²⁺ + 10CO₂ + 8H₂O


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