chemistry (pls show all ur step obtaining)?

2018-05-13 12:34 pm
I've already done a small part of the answer, but idk is it correct or not?
更新1:

I've already done a small part of the answer, but idk is it correct or not? >> I assume 100g=100% so, mass(c)=82.76 g n=m/M n(c)=82.76/12=6.8967 mol ≈ 7 mol so, CnH2n+2=C7H14+2=C7H16 ??? CH₃CH₂CH₂CH₂CH₂CH₂CH₃

回答 (2)

2018-05-13 5:23 pm
✔ 最佳答案
Your answer is incorrect.
This is because you did not consider the hydrogen in the alkane molecule.
You have assume that there were 100 g of the alkane and you have got n = 7
If you assumed that there were 1000 g of the alkane using the same method, you would got n = 70


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Method 1 :

Assume that there are 100 g CₙH₂ₙ₊₂.
Mass of C = (100 g) × 82.76% = 82.76 g
Mass of H = (100 g) × (100 - 82.76)% = 17.24 g

No. of moles of C = (82.76 g) / (12 g/mol) = 6.897 mol
No. of moles of H = (17.24 g) / (1.0 g/mol) = 17.24 mol

Mole ratio C : H
n : (2n + 2) = 6.897 : 17.24
17.24n = 13.79n + 13.79
3.45n = 13.79
n = 4.00
n = 4
2n + 2 = 10

The molecular formula of the alkane is C₄H₁₀.
The condensed structural formula of alkane is CH₃CH₂CH₂CH₃.


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Method 2:

Mass of 1 mole of the alkane = [12.0×n + 1.0×(2n+2)] g = 14n + 2
Mass of C in 1 mole of the alkane = 12.0×n = 12n

Percent by mass of C in the alkane :
[12n/(14n + 2)] × 100% = 82.76%
12n/(14n + 2) = 82.76/100
1200n = 82.76(14n + 2)
1200n = 1158.64n + 165.52
41.36n = 165.52
n = 4.00
n = 4
2n + 2 = 10

The molecular formula of the alkane is C₄H₁₀.
The condensed structural formula of alkane is CH₃CH₂CH₂CH₃.
2018-05-13 5:08 pm
Alkane is 82.76% C and 17.24%H
Take 100g compound
Mol C = 82.76 / 12.011= 6.89 mol C
Mol H in 17.24g = 17.24 / 1.008 = 17.103

Divide through by smaller:
C = 0.403 mol C
H = 1.00 mol H

Resolve fractions , multiply through by 10
C = 4.03
H = 10.0

Alkane is C4H10

CH3CH2CH2CH3


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