✔ 最佳答案
Suppose that gas M in a flask with volume Vₘ, and gas N in a flask with volume Vₙ.
For a fixed amount of gas at constant temperature, P₁V₁ = P₂V₂
Then, P₂ = P₁ × (V₁/V₂)
After the two flasks are connected :
Partial pressure of gas M = (1 atm) × [Vₘ/(Vₘ + Vₙ)] = Vₘ/(Vₘ + Vₙ) atm
Partial pressure of gas N = (1 atm) × [Vₙ/(Vₘ + Vₙ)] = Vₙ/(Vₘ + Vₙ) atm
Total pressure after the two flasks are connected
= (Partial pressure of gas M) + (Partial pressure of gas N)
= [Vₘ/(Vₘ + Vₙ)] + [Vₙ/(Vₘ + Vₙ)] atm
= (Vₘ + Vₙ)/(Vₘ + Vₙ)] atm
= 1 atm