✔ 最佳答案
Common ion effect using calcium chromate and calcium acetate....
With a common ion present, in this case the calcium ion, the solubility of CaCrO4 will be less. This can be "explained" using Le Chatelier's principle.
CaCrO4(s) <==> Ca2+ + CrO4^2- ................. Ksp = ???
If additional calcium ion is added (in the form of Ca(C2H3O2)2), then the equilibrium will move to the left as the concentration of Ca2+ moves closer to what it was originally. This will reduce the solubility of CaCrO4.
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The concentration of CaCrO4 at 20C is 22.5g / 1L.... or .... 22.5g / 156.072 g/mol / 1L= 0.144M
See solubility data here:
https://en.wikipedia.org/wiki/Calcium_chromate
Ksp = [Ca2+][CrO4^2-] = 0.144^2 = 0.0208
CaCrO4(s) <==> Ca2+ + CrO4^2- ................. Ksp = 0.0208
......................... 0.314M...0.144M .................. initial
......................... -x ........... -x .......................... change
........................ 0.314-x....0.144-x .................. equilibrium
Ksp = [Ca2+][CrO4^2-]
0.0208 = (0.314-x)(0.144-x)
x = 0.0616
[Ca2+] = 0.252M
[CrO4^2-] = 0.0824M
The molar solubility of CaCrO4 will be 0.0824M
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Note: Other sources give the Ksp as 7.1x10^-4. Simply substitute 7.1x10^-4 in place of the Ksp derived from Wikipedia and compute the new molar solubility of CaCrO4.
CaCrO4(s) <==> Ca2+ + CrO4^2- ................. Ksp = 7.1x10^-4
......................... 0.314M...0.144M .................. initial
......................... -x ........... -x .......................... change
........................ 0.314-x....0.144-x .................. equilibrium
Ksp = [Ca2+][CrO4^2-]
7.1x10^-4 = (0.314-x)(0.144-x)
x =0.140
[Ca2+] = 0.174M
[CrO4^2-] = 0.0041M
The molar solubility of CaCrO4 will be 0.0041M