A solution contains [Ba+2]=0.75 M and [Pb+2]=0.015 M. What is the [SO4] needed to selectively precipitate the barium?

2018-04-10 8:27 am
BaSO4; Kap= 1.1*10^-10
更新1:

ksp*

回答 (1)

2018-04-10 4:22 pm
BaSO₄(s) ⇌ Ba²⁺(aq) + SO₄²⁻(aq) …… Ksp = [Ba²⁺] [SO₄²⁻] = 1.1 × 10⁻¹⁰

[SO₄²⁻] needed to selectively precipitate the barium
= Ksp / [Ba²⁺]
= (1.1 × 10⁻¹⁰) / 0.75 M
= 1.5 × 10⁻¹⁰ M


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