Chemistry percent yield?

2018-03-19 9:45 am
Gaseous ethane reacts with gaseous oxygen gas to produce gaseous carbon dioxide and gaseous water. If 0.981g of water is produced from the reaction of 2.10g of ethane and 14.1 of oxygen gas, calculate the percent yield of water. Round the answer to 3 sig fig

回答 (2)

2018-03-19 6:36 pm
Molar mass of C₂H₆ = (12.0×2 + 1.0×6) g/mol = 30.0 g/mol
Molar mass of O₂ = 16 × 2 g/mol = 32.0 g/mol
Molar mass of H₂O = (10×2 + 16) g/mol = 18.0 g/mol

Initial number of moles of C₂H₆ = (2.10 g) / (30.0 g/mol) = 0.0700 mol
Initial number of moles of O₂ = (14.1 g) / (32.0 g/mol) = 0.441 mol

2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O
Mole ratio C₂H₆ : O₂ : H₂O = 2 : 7 : 6

If 0.0700 mol C₂H₆ completely burned, O₂ needed = 0.0700 × (7/2) = 0.245 mol < 0.441 mol
O₂ is in excess, and thus C₂H₆ is the limiting reactant/reagent.

Number of moles of C₂H₆ reacted = 0.0700 mol
Maximum number of moles of H₂O formed = (0.0700 mol) × (6/2) = 0.210 mol
Theoretical yield of H₂O = (0.210 mol) × (18.0 g/mol) = 3.78 g

Percent yield of H₂O = (0.981/3.78) × 100% = 26.0%
2018-03-19 10:31 am
Let’s determine the number of moles of water.
n = 0.981 ÷ 18 = 0.0545

Reaction:

C2H6 + O2 → CO2 + H2O
To balance the C’s make 2 CO2. To balance the H’s, make 3 H2O

C2H6 + O2 → 2 CO2 + 3 H2O
To balance the O’s, make 3.5 O2.
C2H6 + 3.5 O2 → 2 CO2 + 3 H2O
To balance the equation, double all of the coefficients.
2 C2H6 + 7 O2 → 4 CO2 + 6 H2O

According to the coefficients, two moles of ethane reacts with seven moles of ethane to make four moles of carbon dioxide and six moles of water.

Ethane = C2H6
Mass of one mole = 24 + 6 = 30 grams
n = 2.10 ÷ 30 = 0.07
For O2, n = 14.1 ÷ 32 = 0.440625

Mole ratio = 0.440625 ÷ 0.07
This is approximately 6.3:1. This is greater than 3.5. This means we have excess oxygen. Let’s use the following proportion to determine the number of moles of water that should have been produced.

2 : 6 = 0.07 * x
x = 0.21
Now we can determine the percent yield.

% yield = 100 * 0.0545 ÷ 0.21
This is approximately 26%


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