N2(g) + 2O2(g) --> N2O4(g)?

2018-01-16 1:53 pm
calculations.?
Into a 500 ml container a chemist introduces 2.0 x 10^-2 mol of N2(g) and 2.0 x 10^-2 mol of O2(g). The container is heated to 900°C, and the following equilibrium is achieved:

N2(g) + 2O2(g) --> N2O4(g)

(A) as equilibrium is reached, 5.9 x 10^-3 mol of N2 is consumed. It's changed in concentration is therefore (calculate)

(B) determine the change in concentration of both O2 and N2O4.

(C) calculate the equilibrium concentrate of each of the three gases.

回答 (3)

2018-01-16 5:27 pm
(A)
Change in [N₂] = -(5.9 × 10⁻³ mol) / (500/1000 L) = -1.18 × 10⁻² mol/L
(The negative sign indicates that N₂ is consumed.)


(B)
N₂(g) + 2O₂(g) ⇌ N₂O₄(g)
Mole ratio N₂ : O₂ : N₂O₄ = 1 : 2 : 1

Change in [O₂] = -(1.18 × 10⁻² M) × (2/1) = -2.36 × 10⁻² mol/L
Change in [N₂O] = +(1.18 × 10⁻² M) × (1/1) = +1.18 × 10⁻² mol/L


(C)
Initial [N₂] = (2.0 × 10⁻² mol) / (500/1000 L) = 4.0 × 10⁻² mol/L
Initial [O₂] = (2.0 × 10⁻² mol) / (500/1000 L) = 4.0 × 10⁻² mol/L
Initial [N₂O₄] = 0 mol/L

[N₂] at equilibrium = [(4.0 × 10⁻²) - (1.18 × 10⁻²)] mol/L = 2.92 × 10⁻² mol/L
[O₂] at equilibrium = [(4.0 × 10⁻²) - (2.36 × 10⁻²)] mol/L = 1.84 × 10⁻² mol/L
[N₂O] at equilibrium = [0 + (1.18 × 10⁻²)] mol/L = 1.18 × 10⁻² mol/L
2018-01-16 4:56 pm
(A)
You're told the change in concentration of N2, so supposing the question meant to ask about the concentration of N2 after the equilibrium is established:
(2.0 x 10^-2 mol of N2 initially) - (5.9 x 10^-3 mol N2 reacted) = 0.0141 mol N2 remains

(B)
(5.9 x 10^-3 mol N2 reacted) x (2 mol O2 / 1 mol N2) = 0.0118 mol O2 reacted (so maybe the answer should be -0.0118 mol)

(C)
(5.9 x 10^-3 mol N2 reacted) x (1 mol N2O4 / 1 mol N2) = 0.0059 mol N2O produced
(2.0 x 10^-2 mol O2 initially) - (0.0118 mol O2 reacted) = 0.0082 mol O2 remains
0.0141 mol N2 remains
2018-01-16 1:54 pm
hm


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