✔ 最佳答案
Molar mass of C₂H₆ = (12.0×2 + 1.0×6) g/mol = 30.0 g/mol
Molar mass of C₃H₄ = (12.0×3 + 1.0×4) g/mol = 40.0 g/mol
Molar mass of CO₂ = (12.0 + 16.0×2) g/mol = 44.0 g/mol
Let y g be the mass of C₂H₆ in the mixture.
Then, mass of C₃H₄ in the mixture = (10 - y) g
Consider the combustion of C₂H₆ :
2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O
Molar ratio C₂H₆ : CO₂ = 2 : 4 = 1 : 2
No. of moles of C₂H₆ burned = (y g) / (30.0 g/mol) = y/30 mol
No. of moles of CO₂ gas produced in the combustion of C₂H₆ = (y/30 mol) × 2 = y/15 mol
Mass of CO₂ gas produced in the combustion of C₂H₆ = (y/15 mol) × (44.0 g/mol) = 44y/15 g
Consider the combustion of C₃H₄ :
C₃H₄ + 4O₂ → 3CO₂ + 2H₂O
Molar ratio C₃H₄ : CO₂ = 1 : 3
No. of moles of C₃H₄ burned = [(10 - y) g] / (40.0 g/mol) = (10 - y)/40 mol
No. of moles of CO₂ gas produced in the combustion of C₃H₄ = [(10 - y)/40 mol] × 3 = (30 - 3y)/40 mol
Mass of CO₂ gas produced in the combustion of C₃H₄ = [(30 - 3y)/40 mol] × (44.0 g/mol) = (33 - 3.3y) g
Total mass of CO₂ gas produced = 30.8 g
(44y/15) + (33 - 3.3y) = 30.8
[(44y/15) + (33 - 3.3y)] × 15 = 30.8 × 15
44y + 495 - 49.5y = 462
5.5y = 33
y = 6
Mass of C₂H₆ in the mixture = 6 g