this reaction in house temperature happend: 2SO3----->2SO2+O2 :delta(H)=+19.8 Is delta(G) negative? Why?
回答 (1)
Qualitative explantion :
2SO₃(g) → 2SO₂(g) + O₂(g)
The entropy change of the above reaction is rather positive because of the increase in the number of gaseous molecules as 2 moles of gaseous molecules are converted to 3 moles.
ΔG = ΔH - TΔS
The value of ΔH is slightly positive. As ΔS is rather positive, ΔG would be negative at house temperature (T = 298 K).
====
Quantitative explanation :
2SO₃(g) → 2SO₂(g) + O₂(g)
ΔS = 2S[SO₂(g)] + S[O₂(g)] - 2S[SO₃(g)] = [2(205) + 249 - 2(256)] J/(mol K) = +147 J/(mol K) = 0.147 kJ/(mol K)
ΔG = ΔH - TΔS = (19.8 - 298 × 0.147) kJ/mol = -24 kJ/mol
收錄日期: 2021-04-18 17:58:57
原文連結 [永久失效]:
https://hk.answers.yahoo.com/question/index?qid=20171208080057AAcd242
檢視 Wayback Machine 備份