✔ 最佳答案
The equation with structure formulae of the reactants and products are shown below.
According to the equation, 6 moles of P-P bonds and 6 moles of Cl-Cl bonds are broken, and 4 × 3 moles of P-Cl bonds are formed.
Energy absorbed in bond breaking = (201 × 6 + 242 × 6) kJ = 2658 kJ
Energy released in bond formation = E(P-Cl) × 4 × 3 = 12 E(P-Cl)
ΔrH = (Energy absorbed in bond breaking) - (Energy released in bond formation)
-1206.9 kJ = (2658 kJ) - 12 E(P-Cl)
Bond dissociation enthalpy for the P-Cl bond, E = (2658 + 1206.9)/12 kJ = 322 kJ