The solubility of PbCrO4 in water at 25°C is measured to be ×1.710−4gL
. Use this information to calculate Ksp for PbCrO4
.?
回答 (1)
Molar mass of PbCrO₄ = (207.2 + 52.0 + 16.0×4) g/mol = 323.2 g/mol
Solubility of PbCrO₄ = (1.7 × 10⁻⁴ g/L) / (323.2 g/mol) = 5.26 × 10⁻⁷ mol/L
PbCrO₄(s) ⇌ Pb²⁺(aq) + CrO₄²⁻(aq)
1 mole of PbCrO₄ dissociates to give 1 mole of Pb²⁺ ions and 1 mole of CrO₄²⁻ ions.
At equilibrium, [Pb²⁺] = [CrO₄²⁻] = 5.26 × 10⁻⁷ mol/L
Ksp for PbCrO₄ = (5.26 × 10⁻⁷)² = 2.77 × 10⁻¹³ = 2.8 × 10⁻¹³ (to 2 sig. fig.)
收錄日期: 2021-04-18 17:56:50
原文連結 [永久失效]:
https://hk.answers.yahoo.com/question/index?qid=20171103030128AAR2ad1
檢視 Wayback Machine 備份