✔ 最佳答案
Initial number of moles of FeCl₃ = (0.6 mol/L) × (18.3/1000 L) = 0.01098 mol
Initial number of moles of AgNO₃ = (0.679 mol/L) × (18/1000 L) = 0.01222 mol
FeCl₃(aq) + 3AgNO₃(aq) → 3AgCl(s) + Fe(NO₃)₃(aq)
Mole ratio FeCl₃ : AgNO₃ = 1 : 3
If 0.01222 mol AgNO₃ completely reacted, FeCl₃ needed = (0.01222 mol) × (1/3) = 0.00407 mol < 0.01098 mol
Hence, FeCl₃ is in excess, and AgNO₃ completely reacts (limiting reagent/reactant).
According to the above equation, mole ratio AgNO₃ : AgCl = 3 : 3 = 1 : 1
Maximum no. of moles of AgCl formed = 0.01222 mol
Molar mass of AgCl = (107.9 + 35.5) g/mol = 143.4 g/mol
Experimental yield of AgCl = (0.01222 mol) × (143.4 g/mol) × 82.5% = 1.45 g