CHEMISTRY PLEASE ANSWER ASAP?

2017-07-25 12:25 am
The oxidation numbers of nitrogen in NH4+, NO2, and NaNO3 are, respectively:
A) -3, +4, +5
B)+3, +5, +4
C)+3, +5, -4
D)-3, -4, +5

回答 (2)

2017-07-25 12:40 am
O.N. = oxidation number

In NH₄⁺ ion :
In an ion, total oxidation number = charge of the ion
(O.N. of N) + (O.N. of H)×4 = charge of the ion
(O.N. of N) + (+1)×4 = -1
Hence, O.N. of N in NH₄⁺ ion = -3

In NO₂ molecule :
In a molecule, total oxidation number = 0
(O.N. of N) + (O.N. of O)×2 = 0
(O.N. of N) + (-2)×2 = 0
Hence, O.N. of N in NO₂ molecule = +4

In compound NaNO₃ :
In a neutral compound, total oxidation number = 0
(O.N. of Na) + (O.N. of N) + (O.N. of O)×3 = 0
(+1) + (O.N. of N) + (-2)×3 = 0
Hence, O.N. of N in NaNO₃= +5


The answer: A) -3, +4, +5
2017-07-25 12:28 am
A) -3, +4, +5
Nitrogen has a higher electronegativity than hydrogen, so in NH4+, the N has a -3 oxidation state. In a nitrate ion, O has a higher electronegativity, and so the N has an oxidation state of +4.


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