If the equilibrium constant for the reaction?

2017-07-10 3:53 pm
If the equilibrium constant for the reaction
A + 2B C + 5/2 D
has a value of 4.0, what is the value of the equilibrium constant for the reaction
2C + 5D 2A + 4B
at the same temperature?

(a) 0.25
(b) 0.063
(c) 1.0
(d) 8.0
(e) 16

I know the answer is B, can someone please explain to me why and show your work.

回答 (2)

2017-07-10 4:10 pm
✔ 最佳答案
A + 2B → C + (5/2)D …… K₁ = [C] [D]^(5/2) / {[A] [B]^2} = 4.0
2C + 5D → 2A + 4B …… K₂ = [A]^2 [B]^4 / {[C]^2 [D]^5} = ?

K₁ = 4.0
[C] [D]^(5/2) / {[A] [B]^2} = 4.0

Reciprocal of the above expression :
[A] [B]^2 / {[C] [D]^(5/2)} = 1 / 4.0
[A] [B]^2 / {[C] [D]^(5/2)} = 0.25

Square of the above expression :
[A]^2 [B]^4 / {[C]^2 [D]^5} = 0.25^2
[A]^2 [B]^4 / {[C]^2 [D]^5} = 0.0625
[A]^2 [B]^4 / {[C]^2 [D]^5} ≈ 0.063 (to 2 sig. fig.)

Hence, K₂ = [A]^2 [B]^4 / {[C]^2 [D]^5} = 0.063

The answer : (b) 0.063
2017-07-10 4:37 pm
Yes


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