✔ 最佳答案
According to
http://occonline.occ.cccd.edu/online/jmlaux/Kf%20Table%20App.%20D.pdf
Kf(Ag(CN)₂⁻) = 5.6 × 10¹⁸
Volume of the final solution = (120.0 + 225.0) mL = 345.0 mL
Initial concentration :
[Ag⁺]ₒ = (2.8 × 10⁻³) × (120.0/345.0) = 9.74 × 10⁻⁴ M
[CN⁻]ₒ = 0.10 × (225.0/345.0) = 6.52 × 10⁻² M
As Kf is very large and [CN⁻]ₒ ≫ [Ag⁺]ₒ,almost all [Ag⁺] is converted to Ag(CN)₂⁻ at equilibrium.
_____________ Ag⁺(aq) ___ + ___ 2CN⁻(aq) ___ ⇌ ___ Ag(CN)₂ ⁻(aq) ___ Kf = 5.6 × 10¹⁸
Initial: _____ 9.74 × 10⁻⁴M ____ 6.52 × 10⁻² M _________ 0 M
Change: ___ -9.74 × 10⁻⁴ M __ -2×9.74 × 10⁻⁴ M ____ -9.74 × 10⁻⁴ M
At eqm: ________ y M _______ 6.33 × 10⁻² M ______ 9.74 × 10⁻⁴ M
Kf = [Ag(CN)₂⁻] / ([Ag⁺] [CN⁻]²)
9.74 × 10⁻⁴ / {y × (6.33 × 10⁻²)²} = 5.6 × 10¹⁸
y = 9.74 × 10⁻⁴ / {(6.33 × 10⁻²)² × (5.6 × 10¹⁸)}
y = 4.3 × 10⁻²⁰
At equilibrium, [Ag⁺] = 4.3 × 10⁻²⁰ M