Are resonance structures sp, sp2, sp3 hybridized?
For like NO3-, since it has resonance in terms of lewis structures, can we say that it is sp2? Or because of the bonding... we can't categorize it as that?
回答 (1)
There are two ways to determine that NO₃⁻ ion is sp² hybridized.
I. By the bonding of the central atom:
According to Valence Bond Theory, sp, sp² or sp³ orbitals make bonds and the unhybridized p orbitals make bonds.
In each of the resonance structures below, the central N atom forms 1 N=O double bonds (containing 1 bond and 1 bond) and 2 N-O single bonds (i.e. 2 bonds). To sum up, the central N atom forms 3 bonds and 1 bond. It can be deduced that the central N atom is sp² hybridized, where the 3 hybridized sp² orbitals form 3 bond and the unhybridized 2p orbital forms 1 bond.
II. By the shape of arrangement of electron pairs:
In each of the resonance structure below, the central N atom forms 1 N=O double bonds and 2 N-O single bonds. According to Valence Shell Electron Pair Repulsion (VSEPR) Theory, the 3 covalent bonds are arranged as trigonal planar. It can be deduced that the central N atom is sp² hybridized by the shape (trigonal planar) of arrangement of electron pairs.
收錄日期: 2021-04-18 16:59:23
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