✔ 最佳答案
In Me₃N, the central atom N has 5 valence electrons, forming 3 N-H bonds and 1 lone pair of electrons (sp³ hybridization). According to VSEPR theory, the 4 electron pairs are arranged tetrahedrally in order to minimize the repulsion between the electron pairs, and thus the molecular shape is trigonal pyramidal. For the shape of Me₃N, all of the 4 options are collect.
In BF₃, the central atom B has 3 valence electrons, forming 3 B-F bonds (sp² hybridization). According to VSEPR theory, the 3 bond pairs are arranged as planar trigonally in order to minimize the repulsion between the electron pairs. This rules out options B and D, in which the 3 B-F bonds in BF₃ are NOT trigonal planar.
In the product Me₃NBF₃, the lone pair electrons on N form a N→F dative bond. Now, the B atom are attached with 3 B-F bonds and one N→F bonds. According to VSEPR theory, the 3 electron pairs are arranged tetrahedrally in order to minimize the repulsion between the electron pairs, and thus the molecular shape with respect to central atom B is tetrahedral. This rules out option A.
Conclusion: Option B and D are ruled out according to the molecular shape of BF₃ while option A is ruled out according to the molecular shape of Me₃NBF₃.
Hence, the answer is C.