Analysis of Transition Metal Oxalate Complex Salt Hydrate?

2017-01-10 11:03 pm
The composition of a hydrated rubidium-salt of chromium (III) oxalate complex ions conforms to the general formula: Rb(x)Cr(C2O4)3●(w)H2O.

A 0.2505 g sample of this compound required 18.70 mL of 0.02566 M KMnO4 solution for the titration of all the oxalate (C2O4)

a) Calculate the number of moles of oxalate in this sample
b) Calculate the number of moles of oxalate per gram of the compound
c) Calculate the molar mass of the compound
d) What is the value of w?

回答 (2)

2017-01-10 11:44 pm
(a)
RbₓCr(C₂O₄)₃ is a neutral compound. Total charges :
(+1)*x + (+3) + (-2)*3 = 0
x = 3
Hence, formula of the compounds is Rb₃Cr(C₂O₄)₃•wH₂O


The equation for the reaction between C₂O₄²⁻ and MnO₄⁻ (in an acidic medium):
2MnO₄⁻(aq) + 16H⁺(aq) + 5C₂O₄²⁻(aq) → 2Mn²⁺(aq) + 8H₂O(l) + 10CO₂(g)
OR: Mole ratio MnO₄⁻ : C₂O₄²⁻ = 2 : 5

Number of moles of KMnO₄ solution = (0.02566 mol/L) × (18.70/1000 L) = 0.0004798 mol
Number of moles of MnO₄⁻ ions reacted = 0.0004798 mol
Number of moles of C₂O₄²⁻ ions reacted = (0.0004798 mol) × (5/2) = 0.001200 mol


(b)
Number of moles of C₂O₄²⁻ ions per g of the compound = (0.001200 mol) / (0.2505 g) = 0.004790 mol/g


(c)
1 mole of Rb₃Cr(C₂O₄)₃•wH₂O contains 3 moles of C₂O₄²⁻.
Number of moles of Rb₃Cr(C₂O₄)₃•wH₂O in the sample = (0.001200 mol) × (1/3) = 0.00040000 mol
Given: Mass of Rb₃Cr(C₂O₄)₃•wH₂O in the sample = 0.2505 g

Molar mass of Rb₃Cr(C₂O₄)₃•wH₂O = (0.2505 g) / (0.00040000 mol) = 626.3 g/mol


(d)
Molar mass of Rb₃Cr(C₂O₄)₃•wH₂O :
85.47×3 + 52.00 + (12.01×2 + 16.00×4)×3 + (1.01×2 + 16.00)w = 626.3
572.47 + 18.01w = 626.3
w = (626.3 - 572.47) / 18.01
w = 2.991 ≈ 3

Hence, w = 3
2017-01-10 11:12 pm
what is the balanced equation for the reaction between KMnO4 and C2O4^2-?

In order to find the moles oxalate from the titration you need to know this first


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