i got test tomorrow!!!?

2016-12-13 6:37 pm
the solubility product constant of bi2s3 is 1x10^-97 and HgS is 4x10^-53.which is less soluble.give your reason

回答 (1)

2016-12-13 10:09 pm
Let x mol/L be the solubility of Bi₂S₃, and y mol/L be that of HgS.

Consider the dissolution of Bi₂S₃ :
Bi₂S₃(s) + aq ⇌ 2Bi³⁺(aq) + 3S²⁻(aq)
At equilibrium : [Bi³⁺] = 2x mol/L and [S²⁻] = 3x mol/L
Ksp(Bi₂S₃)= [Bi³⁺]² [S²⁻]³
1 × 10⁻⁹⁷ = (2x)²(3x)³
108x⁵ = 1 × 10⁻⁹⁷
x = 1.6 × 10⁻²⁰
Solubility of Bi₂S₃ = 1.6 × 10⁻²⁰ mol/L

Consider the dissolution of HgS :
HgS(s) + aq ⇌ Hg²⁺(aq) + S²⁻(aq)
At equilibrium : [Hg²⁺] = [S²⁻] = y mol/L
Ksp(HgS) = [Hg²⁺] [S²⁻]
4 × 10⁻⁵³ = y²
y = 6.3 × 10⁻²⁷
Solubility of HgS = 6.3 × 10⁻²⁷ mol/L < 1.6 × 10⁻²⁰ mol/L = Solubility of Bi₂S₃

HgS is less soluble.


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