✔ 最佳答案
HCOOH(aq) + H₂O(l) ⇌ HCOO⁻(aq) + H₃O⁺(aq) .... Kₐ
Initial concentrations :
[HCOOH]ₒ = 0.10 M
[HCOO⁻]ₒ = [H₃O⁺]ₒ = 0 M
Equilibrium concentrations :
Let [HCOO⁻] = [H₃O⁺] = y M
Then, [HCOOH] = (0.10 - y) M
Kₐ = [HCOO⁻] [H₃O⁺] / [HCOOH]
1.7 × 10⁻⁴ = y² / (0.10 - y)
(1.7 × 10⁻⁵) - (1.7 × 10⁻⁴)y = y²
y² + (1.7 × 10⁻⁴)y - (1.7 × 10⁻⁵) = 0
y = {-(1.7 × 10⁻⁴) ± √[(1.7 × 10⁻⁴)² + (1.7 × 10⁻⁵)]} / 2
Rejecting the negative answer, y = 4.0 × 10⁻³
[HCOOH] = {0.1 - (4.0 × 10⁻³)} M = 0.096 M
[HCOO⁻] = 4.0 × 10⁻³ M