✔ 最佳答案
HAc is a weak acid. The conjugate base Ac⁻ is thus a weak base.
HCl is a strong acid which completely dissociate in water to give H₃O⁺ ions.
Equation for the acid-base neutralization :
Ac⁻(aq) + H₃O⁺(aq) → HAc(aq) + H₂O(l)
Before reaction :
[H₃O⁺] = 0.10 M
[Ac⁻] = 0.50 M
[HAc] = 0.00 M
Obviously, H₃O⁺ is the limiting reactant (limiting reagent) which completely reacts.
After reaction :
[H₃O⁺] = (0.10 - 0.10) M = 0.00 M
[Ac⁻] = (0.50 - 0.10) M = 0.40 M
[HAc] = (0.00 + 0.10) M = 0.10 M
The solution is a buffer because it is the mixture of a weak acid HAc and its conjugate base Ac⁻.
Consider the dissociation of HAc.
HAc(aq) + H₂O(l) ⇌ Ac⁻(aq) + H₃O⁺(aq) .... Ka = 1.8 × 10⁻⁵
pH = pKa - log([HAc]/[Ac⁻]) = -log(1.8 × 10⁻⁵) - log(0.10/0.40) = 5.3