Chemistry mcq?

2016-07-22 10:49 am
A sample of NaOH is contaminated with an inert impurity, 4.00g of this NaOH sample was dissolved in 1 dm3 of water, and a 50cm3 sample of the resulting solution was allowed to react with 50cm3 of 0.1M hcl. The pH of the reaction mixture was found to be 2.0 The percentage purity of the NaOH sample is,

Answer = 80
I need this answer in steps.

回答 (1)

2016-07-22 11:06 am
✔ 最佳答案
Equation for the reaction :
NaOH + HCl → NaCl + H₂O

The pH of the resulting solution is 2.0 :
[H⁺] in the resulting solution = 10⁻²·⁰ = 0.01 M
As HCl is a strong acid, excess [HCl] in the resulting solution = 0.01 M

Volume of the resulting solution = (50 + 50) cm³ = 100 cm³ = 0.1 dm³
No. of moles of excess HCl = (0.01 mol/dm³) × (0.1 dm³) = 0.001 mol

Initial no. of moles HCl = (0.1 mol/dm³) × (50/1000 dm³) = 0.005 mol
No. of moles of HCl reacted with NaOH = (0.005 - 0.001) = 0.004 mol

According to the equation, mole ratio NaOH : HCl = 1 : 1
No. of moles of NaOH in 50 cm³ of the sample solution = 0.004 mol
No. of moles of NaOH in 1 dm³ of the sample solution = (0.004 mol) × (1000/50) = 0.08 mol
No. of moles of NaOH in the sample = 0.08 mol

Molar mass of NaOH = (23.0 + 16.0 + 1.0) g/mol = 40.0 g/mol
Mass of NaOH in the sample = (40.0 g/mol) × (0.08 mol) = 0.32 g

The percentage purity of the NaOH sample = (0.32/4.00) × 100 = 80


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