✔ 最佳答案
You need "3FeO(s)" on the left. The only given equation that mentions FeO(s) is the third one. So multiply the third given equation by 3, then write it backwards:
3 FeO(s) + 3 CO(g) → 3 Fe(s) + 3 CO2(g), ΔH° = -33.0 kJ
You also need "Fe3O4(s)" on the right. The only given equation that mentions "Fe3O4(s)" is the first one. So divide the first given equation by 2, then write it backwards:
3/2 Fe2O3(s) + 1/2 CO(g) → Fe3O4(s) + 1/2 CO2(g), ΔH° = -19.5 kJ
Add the last two equations here:
3 FeO(s) + 3 CO(g) + 3/2 Fe2O3(s) + 1/2 CO(g) →
3 Fe(s) + 3 CO2(g) + Fe3O4(s) + 1/2 CO2(g), ΔH° = -33.0 kJ -19.5 kJ
Combine like amounts on the same side of the arrow, and do the arithmetic for ΔH°:
3 FeO(s) + 7/2 CO(g) + 3/2 Fe2O3(s) → 3 Fe(s) + 7/2 CO2(g) + Fe3O4(s), ΔH° = -52.5 kJ
Now you need to get rid of "3/2 Fe2O3(s)" on the left and "3 Fe(s)" on the right. The given equation that relates those two species is the second one. So multiply the second given equation by 3/2, then write it backwards:
3 Fe(s) + 9/2 CO2(g) → 3/2 Fe2O3(s) + 9/2 CO(g), ΔH° = +34.5 kJ
Add the last two equations here:
3 FeO(s) + 7/2 CO(g) + 3/2 Fe2O3(s) + 3 Fe(s) + 9/2 CO2(g) →
3 Fe(s) + 7/2 CO2(g) + Fe3O4(s) + 3/2 Fe2O3(s) + 9/2 CO(g), ΔH° = -52.5 kJ +34.5 kJ
Cancel like amounts on opposite sides of the arrow, and do the arithmetic for ΔH°:
3 FeO(s) + CO2(g) → Fe3O4(s) + CO(g), ΔH° = -18 kJ
[It would be a good idea to check all my arithmetic concerning ΔH°. I would have guessed the final answer to be positive, so I'm not completely convinced my answer here is correct.]