stuck on this hess's law question?

2016-07-18 5:21 am
2Fe3O4(s) + CO2(g) --> 3Fe2O3(s) + CO(g) delta H° = 39.0 kJ
Fe2O3(s) + 3CO(g) --> 2Fe(s) + 3CO2(g) delta H° = -23.0 kJ
Fe(s) + CO2(g) --> FeO(s) + CO(g) delta H° = 11.0 kJ
calculate deltah for this reaction
3FeO(s) + CO2(g) --> Fe3O4(s) + CO(g)
更新1:

its chemistry!

回答 (4)

2016-07-18 6:55 am
✔ 最佳答案
You need "3FeO(s)" on the left. The only given equation that mentions FeO(s) is the third one. So multiply the third given equation by 3, then write it backwards:
3 FeO(s) + 3 CO(g) → 3 Fe(s) + 3 CO2(g), ΔH° = -33.0 kJ
You also need "Fe3O4(s)" on the right. The only given equation that mentions "Fe3O4(s)" is the first one. So divide the first given equation by 2, then write it backwards:
3/2 Fe2O3(s) + 1/2 CO(g) → Fe3O4(s) + 1/2 CO2(g), ΔH° = -19.5 kJ
Add the last two equations here:
3 FeO(s) + 3 CO(g) + 3/2 Fe2O3(s) + 1/2 CO(g) →
3 Fe(s) + 3 CO2(g) + Fe3O4(s) + 1/2 CO2(g), ΔH° = -33.0 kJ -19.5 kJ
Combine like amounts on the same side of the arrow, and do the arithmetic for ΔH°:
3 FeO(s) + 7/2 CO(g) + 3/2 Fe2O3(s) → 3 Fe(s) + 7/2 CO2(g) + Fe3O4(s), ΔH° = -52.5 kJ
Now you need to get rid of "3/2 Fe2O3(s)" on the left and "3 Fe(s)" on the right. The given equation that relates those two species is the second one. So multiply the second given equation by 3/2, then write it backwards:
3 Fe(s) + 9/2 CO2(g) → 3/2 Fe2O3(s) + 9/2 CO(g), ΔH° = +34.5 kJ
Add the last two equations here:
3 FeO(s) + 7/2 CO(g) + 3/2 Fe2O3(s) + 3 Fe(s) + 9/2 CO2(g) →
3 Fe(s) + 7/2 CO2(g) + Fe3O4(s) + 3/2 Fe2O3(s) + 9/2 CO(g), ΔH° = -52.5 kJ +34.5 kJ
Cancel like amounts on opposite sides of the arrow, and do the arithmetic for ΔH°:
3 FeO(s) + CO2(g) → Fe3O4(s) + CO(g), ΔH° = -18 kJ

[It would be a good idea to check all my arithmetic concerning ΔH°. I would have guessed the final answer to be positive, so I'm not completely convinced my answer here is correct.]
2016-07-18 6:02 am
Reverse the first given thermochemical equation and multiply (1/2) to the both sides :
(3/2)Fe₂O₃(s) + (1/2)CO(g) → Fe₃O₄(s) + (1/2)CO₂(g) ...... ΔH° = -(1/2)(+39.0 kJ)

Reverse the second given thermochemical equation and multiply (3/2) to the both sides :
3Fe(s) + (9/2)CO₂(g) → (3/2)Fe₂O₃(s) + (9/2)CO(g) ...... ΔH° = -(3/2)(-23.0 kJ)

Reverse the third given thermochemical equation and multiply 3 to the both sides :
3FeO(s) + 3CO(g) → 3Fe(s) + 3CO₂(g) ...... ΔH° = -3(+11 kJ)


Add the above three thermochemical equations, and cancel (3/2)Fe₂O₃(s), 3CO(g), 3CO₂(g) and 3Fe(s) on the both sides :
3FeO(s) + CO₂(g) → Fe₃O₄(s) + CO(g) ...... ΔH° = -18 kJ

[Calculations :]
[ΔH° = -(1/2)(+39.0 kJ) - (3/2)(-23.0 kJ) - 3(+11 kJ) = -18 kJ
2016-07-18 5:46 am
42
2016-07-18 5:22 am
What the fvck is this?


收錄日期: 2021-04-18 15:21:08
原文連結 [永久失效]:
https://hk.answers.yahoo.com/question/index?qid=20160717212107AANJvd3

檢視 Wayback Machine 備份