✔ 最佳答案
Reduction half equation : Fe³⁺ + e⁻ → Fe²⁺ ...... [red]
Oxidation half equation : Sn²⁺ → Sn⁴⁺ + 2e⁻ ...... [oxid]
[red] × 2 + [oxid], and cancel 2e⁻ on the both sides. The balanced equation for the overall reaction is :
2Fe³⁺ + Sn²⁺ → 2Fe²⁺ + Sn⁴⁺
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Number of moles of SnCl₂ reacted = (0.1000 mol/L) × (22.40/1000 L) = 0.002240 mol
1 mole of SnCl₂ contains 1 mole of Sn²⁺.
Number of moles of Sn²⁺ reacted = 0.002240 mol
According to the equation above, mole ratio Fe³⁺ : Sn²⁺ = 2 : 1
Number of moles of Fe³⁺ reacted = (0.002240 mol) × 2 = 0.004480 mol
Molar mass of Fe = 55.85 g/mol
Mass of Fe³⁺ reacted = (55.85 g/mol) × (0.004480 mol) = 0.2502 g
Mass percent of Fe³⁺ = (0.2502/0.7450) × 100% = 33.58%