How to do this question.?

2016-05-10 9:58 am
更新1:

A sample of magnesium which is contaminated by mgo reacts completely with o.o540 mol of hcl acid to liberate 600 cm3 of hydrogen.all volumes were measured at r.t.p.calculate percentage by mass of mgo in sample

回答 (1)

2016-05-10 12:37 pm
Consider the reaction between Mg and HCl :
Mg(s) + 2HCl(g) → MgCl₂(aq) + H₂(g) ...... (*)
1 mole of H₂ gas occupies 24000 cm³ in RTP.
No. of moles of H₂ formed = (600 cm³) / (24000 cm³/mol) = 0.0250 mol
Mole ratio Mg : HCl : H₂ = 1 : 2 : 1
No. of moles of Mg = 0.025 mol
No. of moles of HCl used in reaction (*) = (0.0250 mol) × 2 = 0.0500 mol

Consider the reaction between MgO and HCl :
MgO(s) + 2HCl(aq) → MgCl₂(aq) + H₂O(l) ...... (#)
No. of moles of HCl used in reaction (#) = (0.0540 - 0.0500 ) mol = 0.0040 mol
Mole ratio MgO : HCl = 1 : 2
No. of moles of MgO = 0.0040 × (1/2) = 0.0020 mol

Molar mass of Mg = 24.3 g/mol
Mass of Mg = (24.3 g/mol) × (0.0500 mol) = 1.215 g
Molar mass of MgO = 24.3 + 16.0 = 40.3 g/mol
Mass of MgO = (40.3 g/mol) × (0.0040 mol) = 0.161 g
Percentage by mass of MgO = [0.161/(0.161 + 1.215)] × 100% = 11.7%


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