Calculate the equilibrium concentration present.?

2016-02-26 6:30 pm
For the reaction 2 HI(g) <--> H2(g) + I2(g), Kc = 0.016 at 520oC. Calculate the equilibrium concentration of I2 if the initial concentration of HI is 0.50 M and the other two gases are not initially present.

Give your answer in number form only with the correct sig figs. Do not use scientific notation.

回答 (2)

2016-02-26 7:43 pm
✔ 最佳答案
2HI(g) ⇌ H₂(g) + I₂(g)

Initial :
[HI]₀ = 0.50 M
[H₂]₀ = [I₂]₀ = 0 M

At eqm :
[HI] = (0.50 - 2y) M
[H₂] = [I₂] = y M

Kc = [H₂] [I₂] / [HI]
y²/(0.50 - 2y)² = 0.016
y/(0.50 - 2y) = √0.016
0.50 - 2y = y/√0.016
0.50 - 2y = 7.91y
9.91y = 0.50
y = 0.050

At eqm, [I₂] = 0.050 M
2016-02-26 7:13 pm
Use an ICE table for the equilibrium. This gives

Kc = x^2/(0.50 - 2x)^2 = 0.016

solve for x, which is [I2] at equilibrium.


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