Chemistry Le Chateliers Principle Question - Help Please!?

2016-02-19 5:25 pm
When the chemical reaction:

Br2+Cl2 ---> 2BrCl is at equilibrium, what answers best explains how the reaction would shift to the right?

Add Cl2 and add BrCl
Add Br2 and remove BrCl
Remove Br2 and add Cl2
Add Br2 and add BrCl
Remove Br2 and add BrCl


2. When the reaction is at equilibrium, if volume is reduced, what direction does the reaction shift?

to the left
to the right
no change

3. If the ph of an acidic solution is 3, what is the concentration of OH- in molarity?

1 * 10^-11 M
11 M
3M

回答 (1)

2016-02-19 7:26 pm
✔ 最佳答案
1.
Br₂(g) + Cl₂(g) ⇌ 2BrCl(g)

According to Le Chatelier's principle :
Adding Br₂ and Adding Cl₂ would shift the reaction to the right.
Removing Br2 and Removing Cl₂ would shift the reaction to the left.
Adding BrCl would shift the reaction to the left.
Removing BrCl would shift the reaction to the right.

Conclusively, to shift the reaction to the right, add Br₂, add Cl₂ or remove BrCl.
"Add Br₂ and remove BrCl" is the best answer.


2.
Pressure is increased when volume is reduced.
According to Le Chatelier's principle, the reaction would shift to a direction in order to decrease the number of gaseous molecules.
In the equation, there are 2 moles of gaseous molecules on the left, and also 2 moles of gaseous molecules on the right.
No matter what direction that the reaction shifts, the number of gaseous molecules is unchanged.
Therefore, there is no shift in the reaction.

"no change" is the best answer.


3.
pH = 3
[H+] = 1 × 10⁻³ M
[OH-] = Kw/[H+] = (1 × 10⁻¹⁴)/(1 × 10⁻³) = 1 × 10⁻¹¹ M

"1 × 10⁻¹¹ M" is the best answer.


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