0.1M18ml醋酸和0.1M12ml醋酸鈉形成緩衝溶液請問PH值多少?

2015-11-09 8:45 am

回答 (1)

2015-11-09 9:08 pm
✔ 最佳答案
已知:
CH3COOH 的 Ka = 1.8 × 10^-5 (M)

在混合溶液中:
[CH3COOH] = 0.1 × [18/(18 + 12)] = 0.06 M
[CH3COO^-] = 0.1 × [12/(18 + 12)] = 0.04 M

pH
= pKa - log([CH3COOH]/[CH3COO^-])
= -log(1.8 × 10^-5) - log(0.06/0.04)
= 4.6


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