No, the process is not automatic, even your daughter is the sole beneficiary.
Your daughter must apply for grant at the High Court.
Once the court order has been issued to you, your daughter will be allowed to transfer all estates to her name. For real estate properties, she will need to hire a lawyer for the transaction.
Please understand - if the property is used as a collateral (like mortgage), your daughter must discuss the arrangement with the creditor(s) before everything can be finalized. Even it is not a collateral, your daughter must also repay all of your outstanding debts for you. She can only inherit net estate (any excess after deducting your debts).